Reddit reviews Iron Sole
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The Iron Sole will protect your fabric from getting burnt.Universal size to fit different iron sizeProtective cover for ironing all delicate materials, such as velvet, silk, nylon, woolSize: 6.5" x 10"
The reason for them is that the rest of the shirt is at least 90% cotton and after repeated washings cotton on the collar will not allow you to press the shirt so that you have a crisp and sharp collar - it will curl on you or will for a lack of a better word "scorch" the cotton, show the marks of a too hot iron and curl. If you have ever ironed a dress shirt and made the mistake of ironing the collar against the body of the shirt you will see the whitesh/shiny marks it made when heat is applied to the two surfaces. That is why they make these for proper pressing of collars.
You can starch a collar made of denim much easier and have it come out with military corners than you can a cotton/poly blend and it won't look like you seared the collar and / or you don't have to have it dry cleaned to look crisp. This allows you to be in accordance with a straight laced / formal collar while still enjoying the comfort and breathability of cotton, and save some cash.